neuer Blog
The same PA66 formulation, the same conventional short-glass-fiber loading—but the tensile strength of the injection-molded part is only half that of the compression-molded part.
The material engineer was puzzled: If the raw materials and fiber content are exactly the same, why is there such a huge difference in performance?
The answer lies in just two words: fiber length.
During injection molding, high-speed shear forces inside the screw can break glass fibers down to an average length of just 200–400 μm. In contrast, the gentler compression molding process allows the glass fibers to retain lengths of 2–4 mm or even longer.
The reinforcement effect of glass fibers fundamentally depends on the fiber aspect ratio (L/D). The longer the fiber and the higher the aspect ratio, the more efficiently stress can be transferred between the resin matrix and the fibers—ultimately raising the strength ceiling of the composite.
The processing method cuts the fibers. The fiber length determines the performance ceiling.
In 1965, Kelly and Tyson proposed the single-fiber pull-out model, which has since become one of the theoretical foundations of fiber-reinforced composite materials. Its core equation is remarkably simple:
where σc is the strength of the composite, σm is the strength of the matrix, Vf is the fiber volume fraction, and σf is the fiber strength.
Measures the effect of fiber length on stress transfer. When L > Lc, η approaches 1. When L < Lc, η decreases sharply.
Measures the effect of fiber orientation. For perfectly aligned fibers, η₀ = 1; for random in-plane distribution, η₀ = 0.375; and for three-dimensional random distribution, η₀ = 0.2.
The shear stress at the fiber–matrix interface must act over a sufficient embedded fiber length to effectively transfer load from the matrix to the fiber.
where d is the fiber diameter and τ is the interfacial shear strength.
Glass-Fiber-Reinforced PA66 Example
σf ≈ 3400 MPa | d ≈ 13 μm | τ ≈ 30 MPa
Lc ≈ 740 μm
In the Kelly–Tyson model, τ determines the critical fiber length Lc. The higher the interfacial shear strength, the shorter the critical fiber length, allowing shorter fibers to carry loads more effectively.
For glass-fiber-reinforced PP, for example, the use of PP-g-MAH can significantly improve interfacial adhesion and reduce the critical fiber length.
Many compounders focus primarily on glass fiber content (wt%) while overlooking fiber length. This is one of the biggest misconceptions in fiber-reinforced plastics.
The fundamental distinction between Long Glass Fiber (LGF) and Short Glass Fiber (SGF) is therefore not simply fiber content, but the ability to retain a sufficiently high fiber aspect ratio after processing.
| Component | Dosage | Function |
|---|---|---|
| PA66 | Main component | Matrix |
| Short Glass Fiber | Secondary component | Reinforcement |
| PA-compatible glass fiber sizing | As required | Interfacial modification |
| Matrix | Recommended Coupling System | Mechanism |
|---|---|---|
| PP / PE | PP-g-MAH | Improves interfacial bonding between the polyolefin matrix and glass fiber |
| PA / PET | Matrix-compatible glass fiber sizing | Enhances fiber–matrix adhesion |
| Epoxy | Epoxy silane | Promotes chemical interaction with the epoxy matrix |
Check the actual fiber length. SEM analysis of the fracture surface can reveal excessive fiber breakage.
Check glass fiber diameter, surface treatment, screw speed, and processing temperature.
Excessive fiber loading can cause poor dispersion and agglomeration, creating stress-concentration points.
More fiber does not automatically mean higher performance.
The real objective is to preserve sufficient fiber length and build a strong fiber–matrix interface so that the fibers can effectively carry the load.
From PP-LGF and PA66-LGF to high-performance LCF solutions, our technical team can help you select the right fiber length, fiber content, and polymer matrix for your application.
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